Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5145067 | International Journal of Hydrogen Energy | 2017 | 13 Pages |
Abstract
Block poly(arylene ether sulfone) copolymers caring pendent benzyl-quaternary ammonium groups were prepared through multiple-step reaction pathways that involve pre-polycondensation, block copolycondensation, bromomethylation and Menshutkin reactions. The copolymer ionomer based anion exchange membranes (AEMs) with ion exchange capacity (IEC) from 0.75 to 1.10 mequiv gâ1 display relatively large hydroxide conductivities of 45.9-66.1 mS cmâ1 at 80 °C, which are ascribed to the distinct hydrophobic/hydrophilic microphase separation resulted from the block copolymer structures and side-chain type hydrophilic segments. Compared to the corresponding random copolymer based AEM, the block ones have obviously higher stability and larger hydroxide conductivity due to the well-connected ionic nanochannels. Among the AEMs, bQPAE-x7y32 with IEC of 1.10 mequiv gâ1 gives the best performance with high hydroxide conductivity of 66.1 mS cmâ1, low methanol permeability of 4.9 Ã 10â7 cm2 sâ1, large Ï of 4.6 Ã 104 Scmâ3 s, as well as good alkaline stability, respectively.
Related Topics
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Authors
Xueliang Zhang, Pei Chen, Qian Shi, Songsong Li, Feixiang Gong, Xinbing Chen, Zhongwei An,