| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5145821 | International Journal of Hydrogen Energy | 2016 | 6 Pages |
Abstract
A pyridine substituted [2Fe2S] model complex 1 was fully characterized by spectroscopic methods and single-crystal structure analysis. The investigation of complex 1 has demonstrated that a reversible transformation reaction between the complex 1 and (μ-dmedt)Fe2(CO)5(NCCH3), which could mimic the function of the flexible coordination site in the hydrogenases. Electrochemical studies showed complex 1 has the ability to catalyze hydrogen evolution from HOAc and aqueous media at â1.26 V.285
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
![Electrochemical catalysis investigation into the dynamic coordination properties of a pyridine-substituted [2Fe2S] model complex](/preview/png/5145821.png "First Page Preview: Electrochemical catalysis investigation into the dynamic coordination properties of a pyridine-substituted [2Fe2S] model complex")
Authors
Xia Zhang, Tianyong Zhang, Yanhong Wang, Bin Li, Guanghui Zhang, Li Hai, Shuang Jiang,