Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5146127 | International Journal of Hydrogen Energy | 2017 | 14 Pages |
â¢A PET composite membrane was fabricated by electrospinning and solution casting.â¢The PET nanofibers modified with quaternary ammonium-containing SiO2 nanoparticles.â¢Superior thermal stability and ionic conductivity were achieved as compared to PE.â¢The PET-based cell shows better rate capabilities at 0.2-10C both at 25 °C and 55 °C.â¢An improvement of ca. 20% in capacity retention at 1C/1C for 200 cycles at 55 °C.
In this study, a novel polymer electrolyte composite membrane is successfully fabricated using electrospinning and solution casting. The composite membrane comprises two microporous poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) layers plus an intermediate quaternary ammonium-containing SiO2 nanoparticles modified polyethylene terephthalate (PET) nanofibrous nonwoven to form a sandwiched PVDF-HFP/PET/PVDF-HFP composite, which is employed as a separator for lithium-ion batteries (LIBs). The properties of the PET composite membrane are compared with those of commercial PE separator, such as the morphologies, physical properties, and electrochemical performances. According to our results, the composite membrane demonstrates superior thermal stability (thermal shrinkage â¼8%), electrolyte-philicity (contact angle â¼2.9°), electrolyte uptake and retention (282%, 74%), and ionic conductivity (â¼10â3 S cmâ1). The separators are assembled into Li/LiFePO4 cells for electrochemical tests, showing that the PET composite membrane cells exhibit higher capacities than those with the PE separator at 0.2-10C both at 25 °C and 55 °C. The discharge capacity retention and coulombic efficiency of the PET composite membrane cells at 1C/1C for 200 cycles can be respectively enhanced about 20% and 2% at 55 °C as compared to the PE separator cells. These results demonstrate that our prepared PET composite membrane is highly promising for LIB applications.
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