Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5146840 | International Journal of Hydrogen Energy | 2017 | 6 Pages |
Abstract
Dual-phase composite cathodes consisting of La0.8Sr0.2MnO3âδ (LSM) nanoparticles on the Er0.4Bi1.6O3 (ESB) scaffold have been synthesized via an infiltration technique using different polymeric agents for intermediate temperature solid oxide fuel cell (IT-SOFC) applications. It was found that the LSM infiltration with Triton-X yielded well-distributed LSM nano-catalysts (<50 nm) on the ESB surface, while the use of glycine resulted in the highly agglomerated 'layer-like' structure. The nanostructured LSM-ESB fabricated with Triton-X exhibited low electrode resistance of 0.23 Ω-cm2 at 650 °C, which is â¼60% lower than that of the conventional LSM-ESB (0.56 Ω-cm2). Electrochemical impedance analysis revealed that this performance enhancement is primarily attributed to the enhanced charge transfer process of oxygen reduction reactions with homogeneously increased reaction sites in the characteristic nanostructure.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Jin Wan Park, Dong Woo Joh, Byung-Hyun Yun, Kunda J. Samdani, Kang Taek Lee,