Development of large scale unified system for hydrogen energy carrier production and utilization: Experimental analysis and systems modeling

The world's largest class hydrogen energy carrier production, storage, and utilization system has been operated in order to obtain basic data for practical use of the system using renewable energy. In this system, an alkaline water electrolyzer is combined with hydrogenation reactors to produce methylcyclohexane (MCH). Since electrolyzer behavior directly affects hydrogenation reaction, behaviors of the 150 kW class water electrolyzer against fluctuating electricity inputs were experimentally investigated. The cell stack voltage and hydrogen flow rate changed following temporal changes of the input current, whereas the temperature response was slow due to the large heat capacity of the system. Hydrogenation reactors performance using the hydrogen from the electrolyzer are reported. Then, based on the experiment data, a numerical simulation model for the electrolyzer was developed, which predicts the experimental result using fluctuating electricity very well. Furthermore, using the simulator, the heat utilization from the hydrogenation reaction for the electrolyzer warm-up process was investigated.