Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5147507 | International Journal of Hydrogen Energy | 2017 | 11 Pages |
Abstract
In the present study, TiO2 nanoparticles are used as inorganic nanofiller material to prepare nanocomposite proton exchange membrane (PEM). Sulfonated polyvinyl alcohol (SPVA) is synthesized by 4-formylbenzene-1,3-disulfonic acid disodium salt hydrate and water. The cross-linking reaction is performed by glutaraldehyde. These membranes were then dip coated with polyacrylic acid and chitosan alternately and one layer-by-layer (LBL), two LBL and three LBL membranes were prepared. The chemical structure evaluation of SPVA membrane is performed using FTIR. The direct methanol fuel cell (DMFC) catalysts of 10Cu/CeO2 and 10Â Pt-10Â CeO2/C were prepared by reduction reaction and hydrothermal technique. Thus obtained material was spin coated on 2Â ÃÂ 2Â cm2 carbon paper to prepare catalyst anode/cathode. The morphology, size, and purity of catalyst particles are analysed by SEM, UV-visible spectroscopy, FTIR and EDS. Electrochemical analysis is also done to test the performance. Results show that Cu/CeO2 catalyst shows excellent catalysis towards methanol oxidation, which is better than 10Â Pt-10Â CeO2/C particles. The 10Cu/CeO2 catalyst gives peak voltage of 915Â mV for infinite resistance, which is higher than the reported value of the conventional 20Â Pt/C catalyst (810Â mV).
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Authors
Jignasa N. Solanki, Preeti S. Mishra, Z.V.P. Murthy,