Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5147775 | International Journal of Hydrogen Energy | 2017 | 14 Pages |
Abstract
A highly active and stable catalyst/support system is developed by using a two-step process. In the first step, activated carbon composite support (ACCS) is synthesized that retains its activity after accelerated stress test (AST). A 30% Pt/ACCS catalyst shows no loss of mass activity and power density after 5000 cycles at 1.0-1.5Â V while the commercial Pt/C and Pt/290G catalysts show drastic mass activity losses (57.5% and 66.2%, respectively) and power density losses (88.7% and 84.0%, respectively). In the second step, Pt catalyst with a compressive Pt lattice (Ptâ) is synthesized through a USC-developed annealing procedure in which Co atoms previously embedded in the support diffuse into Pt. The 30% Ptâ/ACCS shows high initial power density (rated) of 0.174 gPt kWâ1 and high stability of 24Â mV loss at 0.8Â AÂ cmâ2 with an electrochemical active surface area (ECSA) loss of 42% after 30,000 cycles (0.6-1.0Â V). The support stability under 1.0-1.5Â V potential cycling shows potential loss of 8Â mVÂ at 1.5Â AÂ cmâ2 and ECSA loss of 22% after 5000 cycles. Improved stability and activity of Pt*/ACCS catalyst are due to synergistic effect of catalytic activity and stability of ACCS and formation of compressive Pt lattice catalyst.
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Authors
Taekeun Kim, Tianyuan Xie, Won Suk Jung, Branko N. Popov,