Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5147918 | International Journal of Hydrogen Energy | 2017 | 9 Pages |
Abstract
Developing an effective and facile method to achieve mass production of MoS2 nanostructures with abundant of edges may be the feasible way to meet the increasing demand for hydrogen evolution electrocatalysts. We developed a facile glucose-assisted hydrothermal method to in-situ grow MoS2 nanosheets on the commercial carbon nanofibers (CNFs). The controlled growth of MoS2 on CNFs (MoS2@CNFs) is leveraged to reveal mass ratio- and structure-dependent catalytic activity in the hydrogen evolution reaction (HER). Due to the unique shell structure, abundant edges of the MoS2 layer are exposed as active site, as well as the underlying CNFs effectively improves the conductivity, the resulting MoS2@CNFs hybrid exhibited high electrocatalytic activity in HER. The catalyst demonstrated the lowest overpotential of 52Â mV, the highest current density of 101.49Â mAÂ cmâ2 at â¼200Â mV overpotential and the smallest Tafel slope of 49Â mV/decade, suggesting the Volmer-Heyrovsky mechanism for the MoS2-catalyzed HER.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Anna Li, Yuzhe Hu, Muping Yu, Xiaowang Liu, Maoguo Li,