Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5148430 | International Journal of Hydrogen Energy | 2017 | 12 Pages |
Abstract
Copper (Cu) supported on mesoporous (MSP) ceria catalysts were prepared by deposition-precipitation (DP) method for the preferential CO oxidation of CO in a H2-rich stream (CO-PROX). A MSP ceria support with a high surface area of 293Â m2/g and ordered structure was synthesized by a nanocasting process using MCM-48 as template. All copper-MSP ceria catalysts show high dispersion of Cu and still maintain the fluorite structure of MSP ceria. Moreover, TEM imaging confirmed the three dimensional and long-range ordered pore structure of the Cu-catalysts. The reduction temperature of the Cu-catalysts decreases compared to pure MSP ceria and the reduction of Ce4+ to Ce3+ decreases with increasing copper content. An MSP ceria catalyst with 7Â wt% Cu loading (7Cu/MSP ceria) shows the highest activity with high stability for over 48Â h in various feed components, making it attractive for use as a catalyst in purification of hydrogen.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Sureerat Jampa, Kanapos Wangkawee, Supakorn Tantisriyanurak, Jutamas Changpradit, Alexander M. Jamieson, Thanyalak Chaisuwan, Apanee Luengnaruemitchai, Sujitra Wongkasemjit,