Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5148529 | International Journal of Hydrogen Energy | 2017 | 9 Pages |
Abstract
Composite anion-conducting membranes were prepared from polysulfone with grafted quaternary ammonium groups and dispersed nanoparticles of layered double hydroxide (LDH) with composition Mg0.62Al0.38(OH)2(Cl)0.38·0.6H2O as inorganic filler. Two types of amines were used: small and flexible trimethylamine and bulky and rigid 1,4-diazabicyclo[2.2.2]octane (DABCO). The composite membranes have a distinctly lower water uptake and swelling and they can be hydrated at 60 °C without dissolution. Composites with DABCO have slightly lower water uptake and ionic conductivity than those with TMA. Their mechanical properties in fully humidified conditions are clearly enhanced with especially a nearly 3-fold increase of the Young modulus. In spite of their strongly reduced hydration, the conductivity of the composite membranes is comparable with that of the pristine ionomers, being in the range 2-4 mS cmâ1 at 25 °C. Furthermore, the membranes can be treated in alkaline conditions at 60 °C without losing their properties and the ionic conductivity reaches 30 mS cmâ1 under 95% RH.
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Authors
Maria Luisa Di Vona, Mario Casciola, Anna Donnadio, Morena Nocchetti, Luca Pasquini, Riccardo Narducci, Philippe Knauth,