| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5160152 | Journal of Molecular Structure | 2017 | 6 Pages |
Abstract
We have successfully synthesized palladium(II) complex [Pd(L)Cl] by the reaction of ligand, L-Ch2Ph with Na2PdCl4 in acetonitrile via CS bond cleavage. The distorted square planar geometry is confirmed by single crystal X-ray study. The complex exhibits ligand based thiophenolato to thiyl radical oxidation over the minor possibility of Pd(II)/Pd(III) process. Electronic structure, solution spectrum and redox properties interpreted by DFT and TDDFT calculations.106
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sujan Biswas, Puspendu Roy, Tapan Kumar Mondal,