| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5160630 | Journal of Molecular Structure | 2017 | 14 Pages |
Abstract
A novel hexanuclear CoII complex with the formula of {[Co6(μ3-OH)(Hdhbp)4(dhbp)2(piv)3]·5CH3CN} (1, H2dhbp = 6,6â²-dihydroxy-2,2â²bipyridine, Hpiv = pivalic acid) was obtained and characterized. Single-crystal X-ray analysis shows that complex 1 contains six crystallographic independent CoII ions, which are gathered in the shell to form a [Co6] cluster. The six CoII ions embrace two coordination environments: the distorted octahedron and the vacant octahedron. Magnetic susceptibility of complex 1 was measured and studied.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xiao-Qing Zhao, Dong-Xu Bao, Shuo Xiang, Jin Wang, Chuan Lv, Yun-Chun Li,