Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5161093 | Journal of Molecular Structure | 2017 | 22 Pages |
Abstract
Four new complexes, [Cd(ox)0.5(nim)(2,2'-bipy)]n (1), [Cd(nim)2]n (2), [Cd(nim)2(H2O)2]n (3), and [Zn(nim)2(H2O)2âH2O] (4) (Hnim = 4-nitroimidazolate, H2ox = oxalic acid and 2,2'-bipy = 2,2'-bipyridine) have been prepared. 1-3 exhibit 2D grid networks, while complex 4 shows mononuclear structure. Sensing measurements revealed that 1 and 4 could be a prospective candidate for developing luminescence sensors, which showed significant and exclusive detection ability for the different organic solvents and nitro explosives. It exhibits high sensitivity for 4-nitrotoluene (4-NT) in the presence of other nitro aromatic compounds in DMF by luminescence quenching experiments. Furthermore, the photocatalytic activities of 1-4 were also discussed, in which exhibit efficient catalytic activity for the degradation of methylene violet (MV).178
Related Topics
Physical Sciences and Engineering
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Authors
Jun Wang, Chuan-Ti Li, Chao Bai, Huai-Ming Hu, Gang-Lin Xue,