| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 52525 | Catalysis Communications | 2009 | 4 Pages |
Abstract
The first heterogeneous carbonylative cross-coupling reaction of aryl halides with sodium tetraphenylborate under an atmospheric pressure of carbon monoxide was achieved in DMF at 80 °C or 130 °C in the presence of a catalytic amount of MCM-41-supported bidentate phosphine palladium(II) complex [MCM-41-2P-Pd(II)] to yield unsymmetrical biaryl ketones in good to high yields. This polymeric palladium catalyst can be reused many times without any decrease in activity.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Hong Zhao, Guomin Zheng, Shouri Sheng, Mingzhong Cai,