Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5400331 | Journal of Luminescence | 2014 | 5 Pages |
Abstract
The malonohydrazide based fluorescent probe (7E,8E)-N1â²,N3â²-bis(1-(2-hydroxyphenyl)ethylidene) malonohydrazide (receptor 5) was designed and synthesized. It was confirmed by spectroscopic methods and the single crystal X-ray method. The receptors 5 show strong intramolecular hydrogen bonding which is useful in host-guest complexation. The fluorescence spectra of receptor 5 have shown distinct enhancement with the addition of Ni2+ ion over other surveyed cations. The stability constant was obtained by Benesi-Hildebrand, Scatchard and Connor's fitting methodologies. The 1:1 stoichiometry of the host-guest complexation was confirmed by Job's continuous variation method.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Umesh Fegade, Jaromir Marek, Rahul Patil, Sanjay Attarde, Anil Kuwar,