Article ID Journal Published Year Pages File Type
5411874 Journal of Molecular Liquids 2013 6 Pages PDF
Abstract
► We obtained reliable simulation results for the first three terms of the SW free-energy expansion for ranges ≥ 1.025. ► It is shown that the SW high-temperature expansion, to second order, converges for temperatures greater or equal than 0.5. ► Simulation and a short-range theory are found to agree for the three free-energy terms at the shortest ranges. ► Critical temperatures obtained from the short-range theory have qualitatively sound behavior when the range tends to 1.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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