Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5436232 | Acta Materialia | 2017 | 5 Pages |
Abstract
A general Gibbs-Thomson equation is derived from the complete free energy description of precipitates at grain boundaries, taking into account the excess free energy of the grain boundary - phase boundary junction. In this model, the equilibrium shape of particles shows a strong dependency on the particle size, which gives rise to a deviation from the classical theory of precipitation. The influence of the line tension of triple junctions on the nucleation energy barrier is discussed.
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Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
M. Lin, G. Gottstein, L.S. Shvindlerman,