Article ID Journal Published Year Pages File Type
5436232 Acta Materialia 2017 5 Pages PDF
Abstract

A general Gibbs-Thomson equation is derived from the complete free energy description of precipitates at grain boundaries, taking into account the excess free energy of the grain boundary - phase boundary junction. In this model, the equilibrium shape of particles shows a strong dependency on the particle size, which gives rise to a deviation from the classical theory of precipitation. The influence of the line tension of triple junctions on the nucleation energy barrier is discussed.

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Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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