Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5516695 | Steroids | 2017 | 8 Pages |
Abstract
Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (â)-α-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene-amino acids hybrids, which belong to the series of α-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene-amino acids hybrids, with diastereomeric excess varying from 0 to 100%.
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Authors
K.S. Marenin, Yu.V. Gatilov, A.M. Agafontsev, A.V. Tkachev,