Article ID Journal Published Year Pages File Type
592117 Colloids and Surfaces A: Physicochemical and Engineering Aspects 2015 8 Pages PDF
Abstract

•Polyaniline (PANI)/laponite composite was synthesized via an in-situ chemical oxidation polymerization.•PANI/laponite composites were adopted for electrorheological (ER) application.•PANI/laponite composite exhibited typical ER characteristics with a polarization model.

Polyaniline (PANI)/laponite composites were synthesized via an in-situ chemical oxidation polymerization process using ammonium persulfate as the oxidant in an aqueous solution. Scanning electron microscopy confirmed the morphology of the synthesized composite. The chemical structure of the synthesized product was characterized by Fourier transform infrared spectroscopy. The PANI/laponite composites, which were dedoped to a relatively low conductivity for the electrorheological (ER) measurements, possessed ER characteristics when dispersed in silicone oil at a volume fraction of 10%. The particle structures of the ER fluid under an electric field were analyzed by optical microscopy. The rheological properties, such as the shear viscosity, shear stress and yield stress, which were analyzed using a rotational rheometer under an applied electric field, exhibited typical ER characteristics with a polarization model.

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Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
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