| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 593409 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2013 | 7 Pages |
•Dextran was modified by 1,2-epoxydodecane in aqueous micellar medium.•The importance of using a cationic surfactant was underlined.•The role of epoxide structure on formation of oligomeric by-products was detailed.•The influence of micellar medium on properties of modified dextrans was evidenced.
Hydrophobic modification of dextran (degree of polymerization around 125) by reaction with 1,2-epoxydodecane was investigated in micellar aqueous medium in which epoxide was dispersed under magnetic stirring in the presence of a cationic surfactant. A base catalyst, sodium hydroxide, was added in water. Dextran derivatives with degrees of substitution up to 10% were prepared. Apart from dextran modification, epoxide molecules underwent interfacial oligomerization which led to by-products that had to be extracted by dialysis followed by Soxhlet extraction. Two main reaction parameters influenced the amount of oligomeric by-products, i.e. temperature and surfactant structure. Adsorption of these compounds at air/water interface was studied by surface tension and dilational rheology measurements and compared to that observed with amphiphilic dextrans prepared in homogeneous conditions.
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