Article ID Journal Published Year Pages File Type
593892 Colloids and Surfaces A: Physicochemical and Engineering Aspects 2012 7 Pages PDF
Abstract

In this paper, hierarchical nano/micro-structured Zn–Mg–Al layered double hydroxides (ZnMgAl-LDHs) were successfully synthesized by a one-step urea-method. The morphology, structure, surface area, and adsorption properties of the prepared samples were characterized. The results show that the ZnMgAl-LDHs are of high crystallinity with large surface area, which is favorable for the adsorption. The optimum pH value for the adsorption of methyl orange onto the ZnMgAl-LDHs is 3.0. The adsorption process can be well described by the pseudo-second-order kinetic model. The adsorption isotherm of methyl orange onto the ZnMgAl-LDHs can be depicted by both Freundlich and Langmuir equations, but the latter model matches the results much better than the former one.

Graphical abstractThe hierarchical nano/micro-structured Zn–Mg–Al layered double hydroxides show high adsorption property for removing organic pollutants.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Hierarchical nano/micro-structured Zn–Mg–Al layered double hydroxides were prepared. ► The ZnMgAl-LDHs can effectively adsorb methyl orange. ► The adsorption kinetics of methyl orange follows the pseudo-second-order kinetic model. ► The adsorption isotherm of methyl orange can be depicted by Langmuir equation.

Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
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