| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 594887 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2011 | 5 Pages |
An anti-oxidative polyimide nano-coating on carbon fibers was obtained by electrophoretic deposition of polyamic acid nano-emulsion. The polyamic acid nano-emulsion was synthesized using pyromellitic dianhydride and 4,4-oxydianiline in N,N-dimethylacetamide solution. The polyamic acid nano-emulsion with an average particle size of 320 nm was electrophoretic deposition on carbon fibers and transferred into polyimide after imidization at 280 °C. The properties of polyimide-coated carbon fibers were characterized using field-emission scanning electron microscope, X-ray photoelectron spectroscopy, Fourier transforms infrared spectroscopy and thermogravimetric analysis. The results showed that a continuous and uniform polyimide nano-coating of 80–100 nm was formed on carbon fibers. The polyimide-coated carbon fibers displayed an excellent thermal stability up to 500 °C in air.
Graphical abstract. Sequential and homogeneous polyimide nano-coating of 80–100 nm formed by electrophoretic deposition effectively protect against the oxidation of carbon fiber in air.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Polyamic acid nano-emulsion with particle size of 320 nm in DMAC was obtained and it could be formed polyimide at 280 °C. ► Polyamic acid nano-emulsion was formed a coating layer was about 80–100 nm around the carbon fiber by electrophoretic deposition. ► The PI coating layer could successfully inhibit carbon fiber to be oxidized.
