Article ID Journal Published Year Pages File Type
595066 Colloids and Surfaces A: Physicochemical and Engineering Aspects 2010 5 Pages PDF
Abstract

The surface coating-dependent catalytic activity of icosahedral Au nanoparticles (IAuNPs) for the reduction of 4-nitrophenol by NaBH4 in aqueous solution was investigated. Cetyltrimethylammonium bromide (CTAB)-stabilized IAuNPs with average size of 50 nm were prepared by three-step seeding protocol. The CTAB was then exchanged with several amine derivatives such as pyrrole, pyridine, 2,2′-bipyridine, and 4,4′-bipyridine. The catalytic reaction rates of nanoparticles are in the order of IAuNPs@4,4′-bpy > IAuNPs@2,2′-bpy > IAuNPs@pyridine > IAuNPs@pyrrole > IAuNPs@CTAB, revealing that the catalytic activity of the nanoparticles highly depends on the type and structure of the ligand molecules.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights▶ Icosahedral Au nanoparticles catalyze 4-nitrophenol reduction. ▶ Catalytic activity of the nanoparticles depends on the structure of the ligand. ▶ 4,4′-bipyridine ligand highly accelerates the electron transfer reaction.

Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
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