Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
595066 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2010 | 5 Pages |
The surface coating-dependent catalytic activity of icosahedral Au nanoparticles (IAuNPs) for the reduction of 4-nitrophenol by NaBH4 in aqueous solution was investigated. Cetyltrimethylammonium bromide (CTAB)-stabilized IAuNPs with average size of 50 nm were prepared by three-step seeding protocol. The CTAB was then exchanged with several amine derivatives such as pyrrole, pyridine, 2,2′-bipyridine, and 4,4′-bipyridine. The catalytic reaction rates of nanoparticles are in the order of IAuNPs@4,4′-bpy > IAuNPs@2,2′-bpy > IAuNPs@pyridine > IAuNPs@pyrrole > IAuNPs@CTAB, revealing that the catalytic activity of the nanoparticles highly depends on the type and structure of the ligand molecules.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights▶ Icosahedral Au nanoparticles catalyze 4-nitrophenol reduction. ▶ Catalytic activity of the nanoparticles depends on the structure of the ligand. ▶ 4,4′-bipyridine ligand highly accelerates the electron transfer reaction.