Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
595871 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2009 | 8 Pages |
Abstract
The aim of this work was to evaluate the flocculation of kaolin by using positively charged nonstoichiometric interpolyelectrolyte complex (N-PEC) nanoparticles formed by the interaction of chitosan with poly(sodium 2-acrylamido-2-methylpropanesulfonate) (NaPAMPS) and two random copolymers of AMPS with t-butyl acrylamide, comparative with chitosan. The flocculation efficiency was evaluated by optical density at 500Â nm. The N-PEC nanoparticles were more effective than chitosan in the kaolin separation, especially at low molar ratios between charges, when the flocculation window was more then double at an optimum dose lower than that of chitosan. The main advantage of N-PECs is the increase of critical concentration for kaolin re-stabilization, the N-PEC particles adsorbed on the kaolin surface protecting them more efficient against re-dispersion. The influence of low molar mass electrolytes on the flocculation with N-PECs was also investigated.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Colloid and Surface Chemistry
Authors
Marcela Mihai, Ecaterina Stela Dragan,