| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 596659 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2008 | 4 Pages |
We investigated on cyanine dye (HQ) in Langmuir and Langmuir–Blodgett (LB) films by UV–vis spectra and second-harmonic generation (SHG) methods. UV–vis spectra indicated a uniform film transfer. The significant SHG fringe signal as a function of angle of incidence for Z-type LB films was observed respectively. The refractive indexes at 532 nm and average tilt angle ψ between the molecular (dipolar) axis and surface normal from fitted SHG data are 1.4841, 57° and 1.4775, 53° without and with Cd2+ ions, respectively. The second-order susceptibility χZZZ(2)=42 pm V−1 and 32 pm V−1 for LB films with and without Cd2+ ions are obtained by measuring SHG signals. These high nonlinearities are due to resonant enhancement resulting from the proximity of the second-harmonic wavelength to the absorption band of the films.
