Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
596984 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2008 | 4 Pages |
Abstract
The semiconducting polymer and inorganic metal oxide nanocomposites composed of polypyrrole/titanium dioxide (PPy/TiO2) were synthesized by in situ chemical oxidative polymerization of pyrrole in the presence of TiO2 particles in supercritical carbon dioxide (scCO2). TiO2 nanoparticles with average particle size of 5 nm were surface modified by 3-(trimethoxysilyl)propyl methacrylate (γ-MPS) in order to disperse effectively in CO2 before the polymerization. Transmission electron microscope (TEM) image of the nanocomposite revealed well-dispersed TiO2 particles in PPy matrix. The nanocomposites were also confirmed by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and FT-IR spectroscopy.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Colloid and Surface Chemistry
Authors
Haldorai Yuvaraj, Eun Ju Park, Yeong-Soon Gal, Kwon Taek Lim,