| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 597780 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2006 | 8 Pages |
The production of high-performance ceramics requires the protection of powder particles against chemical reactions. Hydrolysis and oxidation of nanoscaled non-oxidic powders can be impeded by a coating consisting of a dense adsorbed layer of amphiphilic molecules. Using Monte Carlo simulations for a coarse grained model the adsorption equilibrium of differently shaped amphiphiles in apolar and polar solvents is investigated. For estimating the protection capability of the adsorbed surfactant film in aqueous environment we study the diffusion of small hydrophilic particles through the adsorbed surfactant film. The surfactants considered as coating agents differ in the number of hydrocarbon tails. It is found that amphiphiles with a single hydrocarbon tail or at most two branches are more suitable to protect particle surfaces than amphiphiles with three or four branches, although the adsorption energy of amphiphiles with many branches is higher.
