Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
598144 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2006 | 5 Pages |
Abstract
A new surfactant Co(III) chelate, trans-(N-dodecyliminodiacetato)(diethylenetriamine)cobalt(III) chloride (trans-2), which contains two tridentate ligands, N-dodecyliminodiacetic acid and diethylenetriamine, was prepared and characterized. Its structure was established by 1H and 13C NMR, IR, and UV–vis spectroscopy. The Krafft temperature of trans-2 is <23 °C, and its critical aggregation concentration in H2O at 23 °C is (1.3 ± 0.1) × 10−3 M. By cryo-etch high resolution scanning electron microscopy, trans-2 forms aggregates in H2O with sizes of up to 400 nm.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Colloid and Surface Chemistry
Authors
David A. Jaeger, Xiaohui Zeng, Yapin Wang,