| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 607135 | Journal of Colloid and Interface Science | 2014 | 9 Pages |
•Selective modification of shear-stiff, nano-mica platelets.•PMMA coated nano-mica with chains above and below critical entanglement.•Observation of vivid birefringence of a nematic phase with remarkable stability.•Significantly enhanced mechanical properties in spite of non-wetting character.
Optimizing the reinforcement of polymers with nanoplatelets requires optimization of the aspect ratio and the moduli of the filler while providing a complete stress transfer. Employing a novel shear-stiff, nano-mica with large aspect ratio, we focus on maximizing the interfacial interaction between filler and matrix. External surfaces of the nano-mica were selectively modified by a polycationic macro-initiator and two PMMA-polymer brushes of length below and above critical entanglement length, respectively, and the mechanical properties of the three PMMA nanocomposites were measured. The multiple electrostatic anchoring groups of the macro-initiator not only provide reliable adhesion but at the same time allow the variation of the degree of protonation providing a local match between the charge densities of the clay surface and the adsorbed macro-initiator. PMMA coating of the nano-mica via surface initiated polymerization yielded long-term stable suspensions in THF that showed birefringence of a nematic phase.Solution blending of the PMMA coated nano-mica allows for dispersing single clay tactoids in the translucent PMMA nanocomposites at 5 wt% clay loading as determined by transmission electron microscopy (TEM). Although significantly improved mechanical properties could be achieved as compared to nanocomposites made with conventional clay fillers, the full potential – as expressed by Halpin–Tsai equations – of the PMMA coated nano-mica can still not be completely utilized. This is attributed to the non-wetting character of the densely packed PMMA brushes attached to planar nanoplatelets.
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