Article ID Journal Published Year Pages File Type
607803 Journal of Colloid and Interface Science 2013 8 Pages PDF
Abstract
► Organic thiols chemisorbed on gold surface are desorbed spontaneously in UHV at RT. ► HT SAMs underwent phase transitions from c(4 × 2) phase to 4 × √3 phase. ► CHT SAMs underwent phase transitions from (5 × 2√3)R35° phase to disordered phase. ► Structural stability of SAMs in UHV strongly depends on van der Waals interactions.
Keywords
Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
Preview
Spontaneous desorption and phase transitions of self-assembled alkanethiol and alicyclic thiol monolayers chemisorbed on Au(1 1 1) in ultrahigh vacuum at room temperature
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