Preparation and characterization of upconversion luminescent NaYF4:Yb, Er (Tm)/PS bulk transparent nanocomposites through in situ polymerization

The in situ polymerization method was applied to synthesize bulk nanocomposites consisting of hydrophobic NaYF4:Yb, Er (Tm) nanoparticles as the filler and polystyrene (PS) as the host material. The oleic acid stabilized NaYF4:Yb, Er (Tm) nanoparticles and NaYF4:Yb, Er (Tm)/PS nanocomposites have been well characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM), the thermogravimetric analysis (TGA), upconversion photoluminescence spectra and luminescence decays. The well-crystallized NaYF4:Yb, Er (Tm) nanoparticles are spherical with a mean diameter of 40 nm. NaYF4:Yb, Er/PS and NaYF4:Yb, Tm/PS nanocomposites exhibit strong green and blue upconversion photoluminescence upon 980 nm laser excitation, due to the integration of luminescent NaYF4:Yb, Er and NaYF4:Yb, Tm nanoparticles, respectively. These nanocomposites can be potentially used as 3D display materials.

Graphical abstractThe as-prepared β-NaYF4:17%Yb, 3%Er/PS and β-NaYF4:25%Yb, 0.3%Tm/PS nanocomposites show strong green and blue emission, respectively, upon 980 nm laser excitation. These nanocomposites can be potentially used as 3D display materials.Figure optionsDownload full-size imageDownload high-quality image (99 K)Download as PowerPoint slide