Article ID Journal Published Year Pages File Type
612016 Journal of Colloid and Interface Science 2007 7 Pages PDF
Abstract

The controlled heterogeneous modification of cellulose fibers with trifluoroacetic anhydride was investigated. The characterization of the ensuing materials was performed by elemental analysis, FTIR spectroscopy, X-ray diffraction (XRD), thermogravimetry, and surface analysis (XPS, ToF-SIMS, and contact angles measurements). The trifluoroacetylation enhanced significantly the hydrophobic and lipophobic character of the fibers, whereas their thermal stability and cristallinity were only modestly affected by this treatment, except under the most severe conditions for the latter. Their hydrolytic stability to water vapour was also assessed as a function of the air humidity and shown to be lower than that of still liquid water in the case of a saturated atmosphere.

Graphical abstractIt is possible to transform the surface of cellulose fibers from very hydrophilic to highly hydrophobic and lipophobic and to make them regain their pristine properties by a simple hydrolytic treatment.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
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