Article ID Journal Published Year Pages File Type
612117 Journal of Colloid and Interface Science 2007 8 Pages PDF
Abstract

By using a surface-modified templating method, Fe2O3@polypyrrole (PPy) core/shell spindles have been successfully prepared in this paper. The Fe2O3 particles with spindle morphology were initially fabricated as core materials. After the PVP modification, the Fe2O3 spindles were subsequently coated with a tunable thickness layer of PPy by in situ deposition of the conducting polymer from aqueous solution. Hollow PPy spindles were produced by dissolution of the Fe2O3 core from the core/shell particles. High-temperature treatment under vacuum condition covert the hollow PPy spindles into carbon capsules by carbonization of the PPy shell. Transmission electron microscope (TEM), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS) confirmed the formation of the Fe2O3@PPy core/shell particles, PPy and carbon capsules with spindle morphology.

Graphical abstractBy using a surface-modified templating method, Fe2O3@polypyrrole(PPy) core/shell spindles have been successfully prepared in this paper. Hollow PPy spindles were produced by dissolution of the Fe2O3 core from the core/shell particles. High-temperature treatment under vacuum condition coverts the hollow PPy spindles into carbon capsules by carbonization of the PPy shell.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
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