Chemical bath deposition synthesis of sub-micron ZnS-coated polystyrene

The synthesis of ZnS-coated polystyrene composite colloids by the decomposition of thioacetamide in the presence of polystyrene seed particles and metal salt is presented. The chemical bath deposition technique incorporates poly(vinyl pyrrolidone) to inhibit particle aggregation during the synthesis so that core–shell particles with sizes in the low sub-micron range were achieved. The shell thickness was well controlled through the reaction time and core size. ZnS shells were composed of primary crystallites, approximately 5 nm in diameter, which had the zinc blend crystal structure. The porosity of the shells was between 12 and 19%. Accordingly, the effective refractive index of the particles varied between 1.73 and 1.98 at wavelengths above the optical absorption edge of ZnS. Ordered colloidal crystals were produced by convective assembly of the poly(sodium 4-styrenesulfonate) stabilized core–shell particles. Assemblies of ZnS shell–polystyrene core particles are photonic crystal materials which may have applications in optical computing and communications environments.

Graphical abstractThe chemical bath deposition of ZnS shells with well-controlled thickness onto polystyrene seed particles is reported. The composite particles were stabilized with polyanion and assembled into 3D ordered colloidal crystals.Figure optionsDownload full-size imageDownload as PowerPoint slide