Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
613240 | Journal of Colloid and Interface Science | 2006 | 6 Pages |
Abstract
Calcination of a cerium-S-phenylene-O-holmium-O-phenylene-S hybrid copolymer under a vacuum gave cerium oxide–carbon cluster–holmium oxide composite material. The material calcined at 600 °C loaded with Pt particles could decompose water to H2 and O2 with a H2/O2 ratio of 2 under visible light irradiation. ESR spectral examinations of the calcined materials revealed the possibility of a two-step electron transfer in the process of CeO2 → carbon cluster → Ho2O3 → Pt with an oxidation site at CeO2 particles and a reduction site at Pt particles.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Colloid and Surface Chemistry
Authors
Hideo Matsui, Keigo Otsuki, Hiroyoshi Yamada, Tetsuro Kawahara, Masakuni Yoshihara,