Post-combustion CO2 capture with chemical absorption: A state-of-the-art review

Global concentration of CO2 in the atmosphere is increasing rapidly. CO2 emissions have an impact on global climate change. Effective CO2 emission abatement strategies such as Carbon Capture and Storage (CCS) are required to combat this trend. There are three major approaches for CCS: post-combustion capture, pre-combustion capture and oxyfuel process. Post-combustion capture offers some advantages as existing combustion technologies can still be used without radical changes on them. This makes post-combustion capture easier to implement as a retrofit option (to existing power plants) compared to the other two approaches. Therefore, post-combustion capture is probably the first technology that will be deployed. This paper aims to provide a state-of-the-art assessment of the research work carried out so far in post-combustion capture with chemical absorption. The technology will be introduced first, followed by required preparation of flue gas from power plants to use this technology. The important research programmes worldwide and the experimental studies based on pilot plants will be reviewed. This is followed by an overview of various studies based on modelling and simulation. Then the focus is turned to review development of different solvents and process intensification. Based on these, we try to predict challenges and potential new developments from different aspects such as new solvents, pilot plants, process heat integration (to improve efficiency), modelling and simulation, process intensification and government policy impact.

Research highlights▶ Important research programmes in post-combustion CO2 capture with chemical absorption. ▶ Pilot plant studies and modelling/simulation of post-combustion chemical absorption. ▶ Advantages/disadvantages of solvents in CO2 capture with chemical absorption. ▶ Motivations to use process intensification in CO2 capture with chemical absorption. ▶ Challenges and future research directions in post-combustion chemical absorption.