Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6482556 | Bioresource Technology Reports | 2018 | 15 Pages |
Abstract
This paper describes the misuse of Arrhenius pre-exponential factor in the kinetic and thermodynamic studies using thermogravimetry. Standard test method (ASTM E698) has been used recently by many researchers to calculate the pre-exponential factor. ASTM E698 is reserved for differential scanning calorimetry (DSC) and impose many restrictions which have being overlooked by many recently. The obtained pre-exponential factors have been used to describe the thermodynamic behavior during the course of thermal conversions. The objective of this paper is to inform the readers that the pre-exponential factor obtained from the restricted equation can mislead and generate some false thermodynamic data.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Bioengineering
Authors
Imtiaz Ali,