Article ID Journal Published Year Pages File Type
6493015 Journal of Photochemistry and Photobiology A: Chemistry 2012 9 Pages PDF
Abstract
► The lowest excited states of 3,6-disubstituted 1,2,4,5-tetrazines are of nπ* nature, regardless of the substituents. ► The absorption spectra can be adequately interpreted using TD-DFT calculations. ► The weak fluorescence is associated with the presence of a low-energy ππ* excited state. ► UV excitation produces a high-energy ππ* excited state which decays relatively slowly and shows upper-excited state emission.
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