Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6601136 | Electrochemistry Communications | 2016 | 15 Pages |
Abstract
Organic-inorganic hybrid perovskite solar cells have attracted great attention due to their high power conversion efficiency and low cost. However, an anomalous hysteresis effect exists in the perovskite solar cells, especially with TiO2 as the n-type electron extraction layer. In this communication, we prepare two kinds of TiO2 compact layers using Atomic Layer Deposition (ALD) and Spin-Coating (SC) methods and compare their influences on the hysteresis effect. By efficiency comparison and AC impedance spectroscopy study, we find that the thickness and morphology of compact layer have a significant influence on the hysteresis effect. Compared to the SC approach, the ALD prepared compact layer is ultra-thin with uniform morphology and shows small interfacial capacitance and large recombination resistance, meaning reduced interfacial charge accumulation and accelerated electron transport, which would relieve the hysteresis effect.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Liang Chen, Jia-Rui Wang, Li-Qiang Xie, Chao Zhan, Zhi Qiu, Jian-Zhang Zhou, Jia-Wei Yan, Bing-Wei Mao, Zhong-Qun Tian,