Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6601245 | Electrochemistry Communications | 2015 | 4 Pages |
Abstract
Direct membrane deposition was used to produce record platinum catalyst utilization efficiency polymer electrolyte membrane fuel cells. The novel membrane fabrication technique was applied to gas diffusion electrodes with low Pt-loadings of 0.102 and 0.029Â mg/cm2. Under oxygen atmosphere and 300Â kPaabs total pressure, 88Â kW/gPt cathodic catalyst utilization efficiency with a symmetrical Pt-loading of 0.029Â mg/cm2 on the anode and cathode side was achieved. This is 2.3 times higher than the Pt-utilization efficiency of a reference fuel cell prepared using a commercial Nafion N-211 membrane and identical catalyst layers, emphasizing that the improvement is purely attributable to the novel membrane fabrication technique. This value represents the highest Pt-utilization efficiency reported in literature. The results strongly motivate the application of employing direct membrane deposition techniques to prepare low resistance polymer electrolyte thin films in order to compensate for kinetic losses introduced when using low catalyst loadings.
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Authors
Matthias Breitwieser, Matthias Klingele, Benjamin Britton, Steven Holdcroft, Roland Zengerle, Simon Thiele,