Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6610809 | Electrochimica Acta | 2015 | 20 Pages |
Abstract
Noble metal network nanostructures with three-dimensionally (3D) interconnected architectures are attracting much attention because of their unique catalytic, electrical, and optical properties. In this work, we report a facile ethylenediaminetetraacetic acid (EDTA) mediated chemical reduction route for the synthesis of high-quality palladium (Pd) nanowire networks (Pd-NWNWs). During the synthesis, EDTA interacts with PdCl2 to generate EDTA-PdII complex, which efficiently decreases the reduction potential of PdII precursor. The slow reduction rate is crucial for the generation of Pd nanowires. The morphology, composition, and structure of Pd-NWNWs are fully investigated by various physical characterizations. The electrocatalytic activity of Pd-NWNWs for the hydrazine oxidation reaction (HOR) is also studied by cyclic voltammetry, electrochemical impedance spectroscopy, and chronoamperometry, etc. Compared to commercial Pd black, Pd-NWNWs exhibit remarkably improved electrocatalytic activity and stability for the HOR.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Fumin Li, Yigang Ji, Shiman Wang, Shuni Li, Yu Chen,