Article ID Journal Published Year Pages File Type
6998442 Journal of Colloid and Interface Science 2014 8 Pages PDF
Abstract

- Charge development at goethite surfaces was tracked in mixed NaCl/NaClO4 solutions.
- Cl− promotes charge development more than ClO4-.
- Molecular dynamics show that perchlorate broadens the interfacial region.
- Surface charge data are modeled using a thermodynamic adsorption model.
- A combination of ion-specific compact layer capacitances predicts surface charge.
Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
Authors
, ,