Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
701780 | Diamond and Related Materials | 2016 | 8 Pages |
•Multiscale characterization of heteroepitaxial diamond grown on iridium•Crystal mosaicity probed with XRD reciprocal space mappings on asymmetrical nodes•Correlation between XRD, Raman and CL analysis•Threading dislocation counting with non-destructive CL images•Splitting and shift of free excitons due to anisotropic strain at the micrometer scale
The present study provides a multi-scale investigation of the crystalline quality and the structural defects present in heteroepitaxial diamond films grown on iridium/SrTiO3 (001) substrates by microwave plasma assisted chemical vapor deposition. X-ray diffraction, Raman spectroscopy and low temperature cathodoluminescence are combined to accurately characterize the mosaicity, the density of dislocations and the residual strain within the films. X-ray diffraction and Raman results confirm a structural quality at the state-of-the-art according to the epitaxial relationship 〈100〉diamond(001) // 〈100〉iridium(001) // 〈100〉SrTiO3 (001). In addition, Raman and cathodoluminescence observations on cross-sections reveal the presence of local strain.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide