Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
70948 | Journal of Molecular Catalysis B: Enzymatic | 2009 | 5 Pages |
Abstract
The chemical selectivity between Markovnikov addition and acylation in the reaction of thiols and vinyl esters were developed. The addition reaction was efficiently catalyzed by CAL-B at 50 °C in isopropyl ether, affording the Markovnikov adducts with good yields. Acylation was carried out under the catalysis of d-amino acylase in DMF at 50 °C. A series of thioethers and thioesters were synthesized via the controllable enzymatic methods.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Feng-Wen Lou, Bo-Kai Liu, Jun-Liang Wang, Qian Pan, Xian-Fu Lin,