Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7138947 | Sensors and Actuators B: Chemical | 2018 | 8 Pages |
Abstract
Hierarchical arrays of ZnO/Si nanowires were prepared through very convenient two-step solution method on silicon substrates. The tree-like nanowire structures showed high crystal quality, where well aligned Si nanowires were grown vertical to the substrate surface, whereas uniform assembly of branched ZnO nanowires was grown normal to the Si nanowires (backbones). Raman analysis indicated that among all the specimens having identical chemical compositions and dimensions but different forms (thin films or nanowires), Ag-decorated hierarchical arrays of ZnO/Si nanowires possessed the highest intensity peak in surface enhanced Raman scattering spectra. Such arrays demonstrated exceptional ability of detecting Rhodamine 6â¯G, limiting to a value as low as 1Ã10â8 mol/L and an enhancement factor up to 1.5â¯Ãâ¯104. Both, experimental designing and band structure analysis indicated that electromagnetic effect of the localized surface plasmon resonance of Ag nanoparticles caused eight times enhancement, whereas chemical effect of hierarchical arrays of ZnO/Si nanowires played a more critical role in the high Raman sensitivity. Our results would be helpful to better understand the enhancement mechanisms and meanwhile, could be extended for further potential applications of hierarchical semiconducting nanowires.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Shengli Huang, Bing He, Xiaolan Yan, Imran Khan, Jiayuan Wang, Mengyao Gao, Jinshen Lan, Shuping Li, Junyong Kang,