| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7148858 | Sensors and Actuators B: Chemical | 2013 | 9 Pages |
Abstract
A cholesterol-based salicylidene Schiff base derivative CDBHA (cholesterol 2-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)acetate) with excellent multi-stimuli-responsive properties has been designed and synthesized. CDBHA can readily self-assemble into gels with nanofiber structures in several kinds of organic solvents. Compared to their corresponding solutions, the generated gels exhibited a significantly enhanced emission. This typical aggregation-induced emission (AIE) property is a result of the cooperative formation of the J-aggregates and inhibition of the intramolecular rotation. In addition, CDBHA gels are intelligent. On one hand, gel-sol transitions together with noticeable fluorescence changes can be reversibly modulated by alternating rounds of cooling and heating. On the other hand, the gels show a highly selective dual-responsive behavior to Zn2+ through a gel-sol transition, a turn-on of fluorescence and an efficient dual-responsive behavior to Fâ through gel-sol transition and color changes.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Libin Zang, Hongxing Shang, Dayan Wei, Shimei Jiang,