| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 72289 | Microporous and Mesoporous Materials | 2016 | 6 Pages |
Abstract
•F atoms were likely to have been coordinated to nickel.•Approximately half of F− ions were removed by calcination.•A considerable unit cell shrinkage, observed in VSB-1 after calcination, is explained.
The local environment of nickel in VSB-1, a nanoporous nickel phosphate material, was systematically investigated by a combination of X-ray absorption spectroscopy and multiple complementary techniques before and after calcination. A considerable unit cell shrinkage observed in VSB-1 after calcination is explained by the loss of F− ions and the corresponding changes in the nickel environment.
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Jianqiang Wang, Zhendong Wang, Zhenlong Jia, Gen Meng, Zhongqiang Xu, Weimin Yang, Anatoly I. Frenkel,