Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
72695 | Microporous and Mesoporous Materials | 2014 | 8 Pages |
Abstract
•Synthesis of a novel triquaternary organic structure directing agent with facile organic chemistry.•Synthesis of aluminophosphate and silicoaluminophosphate LTA.•Synthesis of germanosilicate LTA.•Use of molecular modeling to compute the conformation of the organic in the microporous materials.
The use of triquaternary organic structure directing agents (OSDAs) for the synthesis of microporous materials is relatively unexplored. Here a triquaternary OSDA prepared by reacting 1,2-dimethylimidazole with 1,3,5-tris(bromomethyl)benzene promotes the formation of LTA in the aluminophosphate or germanosilicate reaction chemistries.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Joel E. Schmidt, Stacey I. Zones, Dan Xie, Mark E. Davis,