| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 73157 | Microporous and Mesoporous Materials | 2014 | 8 Pages |
•Microporous coordination polymers having various shaped apertures were synthesized.•Porous structures are precisely characterized crystallographically.•The substituents exert a notable influence on the pore depending on phenylene units.
Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.
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