Article ID Journal Published Year Pages File Type
73543 Microporous and Mesoporous Materials 2013 8 Pages PDF
Abstract

•Seeded synthesis of zeolite Beta.•Synthesis of zeolite Beta nanocrystals in fluoride media.•Comparative study of physicochemical properties of zeolite Beta crystals synthesized in hydroxyl and fluoride media.•m-Xylene conversion.

This study reports on the seeded synthesis of zeolite Beta in fluoride media. Crystal growth kinetics of the material as a function of seed content, crystallization temperature and Si/Al ratio of the initial gel is studied. After the optimization of crystallization conditions a highly crystalline material with crystal size 100–300 nm is synthesized. A counterpart zeolite Beta sample with similar characteristics is obtained in hydroxyl media. The physicochemical properties of fluoride and hydroxyl media syntheiszed zeolites are compared as particular attention is paid to the nature, number and distribution of their active sites. Zeolite Beta sample synthesized in fluoride media exhibits larger number of Broensted acid sites, while the concentration of Lewis acid sites is higher in the zeolite synthesized in hydroxyl media. The two materials are tested in m-xylene transformation, where zeolite Beta synthesized in fluoride medium shows superior performance. The set of experimental data unambiguously proves that seeded synthesis of zeolites in fluoride medium is a promising alternative of the conventional zeolite synthesis in hydroxyl medium.

Graphical abstractA comparative study of the physicochemical properties and catalytic performance in m-xylene transformation of zeolite Beta synthesized in fluoride and hydroxyl media is performed.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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